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Optical films cast from styrenic fluoropolymer solutions

Invented by: Bin Wang
Kingsport, TN

Thauming Kuo
Kingsport, TN

Douglas Stephens McWilliams
Piney Flats, TN

Frank W. Harris
Boca Raton, FL

Ted Calvin Germroth
Kingsport, TN

Jiaokai Jing
Uniontown, OH

Dong Zhang
Uniontown, OH

Xiaoliang Zheng
Hudson, OH Applicant: Name City State Country Type Wang

Originally Assigned to: Akron Polymer Systems, Inc.
Akron, OH
[Now assigned to . . .]

Issued:2014-11-18
Filed:2012-05-01
Application No:13461372
Examined by:Vargot; Mathieu D.

A method for casting a styrenic fluoropolymer film on a substrate includes preparing a polymer solution by dissolving the fluoropolymer in a solvent or solvent blend whose Hansen solubility parameters (HSPs. MPa.sup.1/2) satisfy the following relations: |SP.sub.b-SP.sub.p|<5, |SP.sub.b-SP.sub.s|<4, |SP.sub.b(H)-SP.sub.p(H)|<7, and 2<|SP.sub.b(H)-SP.sub.s(H)|<10 wherein SP.sub.b, SP.sub.p, SP.sub.s, are the total Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; SP.sub.b(H), SP.sub.p(H), and, SP.sub.s(H) are the hydrogen-bond Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; wherein the fluoropolymer comprises a moiety of: ##STR00001## wherein R.sup.1, R.sup.2, and R.sup.3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R.sup.1, R.sup.2, and R.sup.3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring.

[pdf] U.S. Pat. No. 8,889,043

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